Five people died after looters torched a garment factory near Chile's capital Santiago, bringing the death toll in violent protests to at least seven.
The military and police used tear gas and water cannon against protesters and a curfew was imposed in major cities.
A state of emergency already in place in Santiago is to be extended to cities in the country's north and south.
The unrest, sparked by a now-suspended metro fare hike, has widened to reflect anger over living costs and inequality.
There is set to be major disruption on Monday with many banks, schools and shops expected to remain closed.
What is happening on the ground?
Firefighters say they found five bodies inside the garment factory burned by rioters in a suburb of Santiago. Earlier reports suggested three others had died in a supermarket fire in Santiago on Saturday.
Interior Minister Andrés Chadwick said at least seven people had died in incidents related to the protests, without giving details.
There had been 70 "serious incidents of violence", including 40 lootings of supermarkets and other businesses. Two people also suffered gunshot wounds after a clash with police, officials say.
"We're facing a real escalation that is undoubtedly organised to cause serious damage to our country and the lives of each of its citizens," the minister said.
Some 10,500 police and soldiers have been deployed to the streets, he added, while officials report more than 1,400 arrests.
In several cities on Sunday, protesters set more buses on fire, smashed up metro stations and clashed with riot police. A night-time curfew was imposed in the areas of Santiago, Valparaíso, Coquimbo and Biobío.
A state of emergency will be applied to Antofagasta, Valparaíso, Valdivia, Chillán, Talca, Temuco and Punta Arenas, allowing authorities to restrict people's freedom of movement and their right to assembly.
In Santiago, almost all public transport was suspended and some flights at the international airport were cancelled or rescheduled because of insufficient crew.
At least one line of the city's metro was expected to reopen on Monday after the entire system was closed on Friday because of the damage caused during the unrest, the worst to hit one of Latin America's most stable countries in decades.
What does the president say?
President Sebastián Piñera, a billionaire conservative, has been criticised for his response to the protests, the most severe crisis of his current term.
In a TV speech, he said people who were causing fires, setting up barricades and looting were "criminals".
"We're very aware that [those behind the riots] have a degree of organization, logistics, typical of a criminal organization," he said. "I call on all my compatriots to unite in this battle against violence and delinquency."
Mr Piñera - who took office in March 2018 after having served as president between 2010 and 2014 - has deployed soldiers and tanks for the first time since 1990, when Chile returned to democracy after the dictatorship of Augusto Pinochet.
President's language adds fuel to the flames
Analysis by Vanessa Buschschlüter, BBC News Online Latin America editor
"We're at war against a powerful and implacable enemy who doesn't respect anything or anyone, and who's willing to use limitless violence and criminal acts." That is how President Piñera described the protests late on Sunday.
While some of the footage of violent clashes between the security forces and protesters do resemble those coming out of a war zone, the reaction to Mr Piñera's description has been scathing with opposition politicians calling it "pathetic" and "irresponsible".
But more important is the effect those words have had on the protesters. If they already felt ignored by the government, President Piñera labelling them as criminals in their eyes proves how little he cares about their concerns.
With the protest movement gaining momentum while still lacking clear leaders and Mr Piñera's language further stoking the flames, the chance of any meaningful dialogue seems to slip further away.
What is the background?
The unrest has exposed divisions in the nation, one of the region's wealthiest but also one of its most unequal, and intensified calls for economic reforms.
Source : BBC